*Completely personal and I'm trying to recollect fifteen year old impressions
EDIT:
As I just discovered, I also meant Heretic. I think I haven't actually played Hexen. For authenticity sake, I'm leaving the original post as is, even though it says Hexen ...
But:
IIRC, Hexen didn't have the level design in a quality that Doom had. Also, the sound effects of Doom were utterly brilliant. Not only the shotgun, but most of the weapons, the grunts of the monsters, the satisfying sound of the pick-ups, etc. The sound effects of Hexen were rather annoying.
Also, combat was faster and more intense. From what I recall, Hexen had less "hoards of monster". Also, the brilliant "shotgun gameplay" (move, shot, kill, strafe, shot, evade, shot, kill) was gone due to not having a similar weapon. It was more "chipping away" of the enemies health.
The setting of Doom was better and with Episode progressing more diverse. From the techno style of the beginning to the nightmarish looks of Hell it just looked better than the brown in brown of Hexen.
Better monsters. Every monster in Doom was unique and fun to fight and kill. Doom II is a sign of how good the Doom 1 cabaret was because even the added monsters for Doom II felt cheap. The only shitty monster of Doom 1 I can think of is the Spiderdeamon.
And: Shotgun and Chainsaw. Nuff said.
Doom just felt better designed and had more fluent, concerted gameplay. Hexen felt like a fantasy cash in.
Edit: Typo
Post edited November 27, 2012 by SimonG